1.1a conduct practical investigations to observe and measure the quantitative relationships of chemical reactions, including but not limited to:
– masses of solids and/or liquids in chemical reactions
During a chemical reaction, the atoms are rearranged from the reactants (starting substances) to the products (end substances). Chemical bonds between atoms are broken, and new bonds are formed, but the number of atoms in the reactants is equal to the number of atoms in the products: the total mass of the reactants at the beginning is equal to the total mass of products after the reaction.
No atoms are created or destroyed, therefore no matter, is lost or gained. (BBC Bitesize, 2014).
Open and closed systems
Systems can be closed or open:
A closed system is one where a quantity or series of quantities cannot enter or leave the system. In a closed system, the mass of the system cannot change over time.
An example is a closed bottle of soft drink. What happens to the "fizz" over time?
An open system is one where a quantity or series of quantities can enter or leave the system to a significant degree. In an open system, the mass of the system can change over time.
An example is an open bottle of soft drink. What happens to the "fizz" over time?
TASK 1.1.1 Design experiments
Metals react with dilute acids to form hydrogen gas.
Bicarb soda (sodium hydrogen carbonate) reacts with vinegar to form carbon dioxide gas.
Hydrogen peroxide decomposes into water and oxygen gas.
Copper sulfate and sodium hydroxide solutions form a copper hydroxide precipitate when they are combined.
Select TWO of these reactions and design separate experiments to test the conservation of mass.
TASK 1.1.2A View video:
Conservation of Mass [6.04 mins] https://www.youtube.com/watch?v=v2rL7rrk5qk&list=PLeFSFSJ9WqSBlS5riye9fg1b6SlJQ00h4&index=2
TASK 1.1.2B Complete Quiz
https://www.footprints-science.co.uk/index.php?quiz=Law_of_conservation_of_mass
TASK 1.1.3 Practical: Modelling conservation of mass: making a biopolymer
Equipment and Materials:
100mL measuring cylinder, 250mL conical flask, thermometer, small test tube, rubber stopper, electronic balance, water bath
milk, vinegar
Procedure:
Zero the balance.
Measure 50mL of milk with the measuring cylinder. Pour the milk into the flask.
Sit the flask in the water bath. Place the thermometer in the flask.
Heat to approximately 50C.
Carefully remove the flask and weigh it on the balance. Record the mass.
Measure approximately 10mL of vinegar and transfer to the test tube.'Place the test tube in the flask.
Stopper the flask and record the total mass.
Very firmly hold the stopper in place and invert the flask. Mix carefully to mix the two liquids.
Record the total mass after the reaction.
Q1. Is this a closed or an open system? Therefore what would we expect to happen to the mass?
Q2. Was there a difference in mass before and after the reaction? Explain this.
TASK 1.1.4 Calculations:
1. A solid has a mass of 25g is mixed with 60g of a solution. A chemical reaction takes place and a gas is produced. The final mass of the solid mixture is 75g. What is the mass of the gas released? (Dearborn Schools, 2015)
2. If 100g of a substance reacts with 70g of another substance, what will be the mass of the products after the reaction? (Dearborn Schools, 2015)
3. A student adds 15g of baking soda to 10g of acetic acid in a beaker. A chemical reaction occurs and a gas is given off. After the reaction, the mass of the products remaining in the beaker is 23g. Has the mass been conserved in this reaction? Explain. (Dearborn Schools, 2015)
Mass reactants = mass products 25g + 60g = 75g + x x= 10g
Mass reactants = mass products 100g + 70g = x x= 170g
Mass reactants = mass products 15g + 10g =25g, not 23g. The mass of the products would be 25g, but 2g of gas has escaped this open system.
1.1b conduct practical investigations to observe and measure the quantitative relationships of chemical reactions, including but not limited to:
– volumes of gases in chemical reactions
The volume of gas produced can be used to follow the course of a reaction. Gas volumes can be measured using a gas syringe or an upturned measuring cylinder or burette.
The mass of gas produced can be measured using a sensitive balance.
TASK 1.1.5 View video:
Collecting gases: https://www.youtube.com/watch?v=1Ux1Z3XgRqE&index=1&list=PLeFSFSJ9WqSBlS5riye9fg1b6SlJQ00h4 5:27
TASK 1.1.6 Practical: Conservation of Mass with gases
1.2a relate stoichiometry to the law of conservation of mass in chemical reactions by investigating:
– balancing chemical equations
Using a balanced chemical equation to calculate amounts of reactants and products is called stoichiometry. It is a super technical-sounding word that simply means the amalgamation of Chemistry and Mathematics (Khan Academy, 2016).
Stoichiometric calculations are based on the law of conservation of mass.
The total mass of all products is equal to the total mass of all reactants in a chemical reaction.
Balancing chemical equations help ensure we have followed the law of conservation of mass.
2H2(g) + O2(g) --> 2H2O(l)
Reactants Products
A chemical equation should be balanced on both sides. A chemical equation shows us the substances involved in a chemical reaction: the substances that react (reactants) and the substances that are produced (products). In general, a chemical equation looks like this:
Reactants --> Products
According to the law of conservation of mass, when a chemical reaction occurs, the mass of the products should be equal to the mass of the reactants. Therefore, the amount of the atoms in each element does not change in the chemical reaction, the chemical equation that shows the chemical reaction needs to be balanced. A balanced chemical equation occurs when the number of the atoms involved in the reactants side is equal to the number of atoms in the products side (Study, 2016).
In general, to balance an equation, here are the things we need to do:
Count the atoms of each element in the reactants and the products.
Use coefficients; place them in front of the compounds as needed.
Where possible, leave an element until last as any coefficient placed in from of an element only affects that element (eg 2Li) whereas any coefficient placed in front of a compound affects all atoms in the compound (eg 2NaCl)
The steps are simple, but it is sometimes a process of trial and error.
Task 1.2.1A: View PPT (right https://drive.google.com/open?id=1wgBIwqcwe1uqVd3FTLPxVJkQIuZgDmA8 )
TASK 1.2.1B
View Atomi videos and complete Quizzes for Equations Basics and Balancing Equations:
https://learn.getatomi.com/subscriptions/13876/classes/1579536/modules/3349/posts/3390
Task 1.2.1C: View videos as needed
Balancing equations 1 https://www.youtube.com/watch?v=bDiBHbM0Its 7:32
Balancing equations 2 https://www.youtube.com/watch?v=Al5EFBYJf-0 8:55
TASK 1.2.2: Check in question
1. In the reaction: 4Li(s) + O2(g) → 2Li2O(s)
a. what is the product?
b. what are the reactants?
c. what does the “(s)” after the formula of lithium oxide signify?
d. what is the coefficient of the lithium metal?
TASK 1.2.3A: Review worked examples below
TASK 1.2.3B: Practise
TASK 1.2.4 Walk through tutorial (if needed):
TASK 1.2.5 Pearson Review:
Complete
6.1 Review p212
Key Qs p212
TASK 1.2.6: Check in equations
4 6 --> 2 6
1 2 --> 1 2
1 2 --> 1 4
2 1 --> 1 2
4 5 --> 4 6
1.2b relate stoichiometry to the law of conservation of mass in chemical reactions by investigating:
– solving problems regarding mass changes in chemical reactions
This is where we bring stoichiometry and the law of conservation of mass together. When a chemical reaction is written as an equation, and is balanced, we can get an idea of the relative amounts of each substance present as either reactant(s) or product(s). As we learn more about stoichiometry, we will be able to make direct calculations to demonstrate the conservation of mass in any chemical reaction (Chan, et al., 2018).
Chemical reactions may involve one or more products being in a different state at room temperature to the reactant(s). Chemists need to take into account the different states which may be produced when applying the law of conservation of mass to the reaction. In addition to the balancing of chemical equations, we will also use subscripts to show these states (Chan, et al., 2018).
Task 1.2.7: View videos as needed
Stoichiometry https://www.youtube.com/watch?v=UIWMKkWoJPU&index=5&list=PLeFSFSJ9WqSBlS5riye9fg1b6SlJQ00h4 5:54
Mass changes in chemical reactions https://www.youtube.com/watch?v=ClmESFa-5hc&index=4&list=PLeFSFSJ9WqSBlS5riye9fg1b6SlJQ00h4 7:01
TASK 1.2.8: Pearson Review
6.2 Review p217
Key Qs p217
Chapter Review p218